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Partial Charges Give Clues About Electron Flow

There’s a hidden layer of detail beneath chemical structures that students new to organic chemistry often miss.

I’m talking about partial charges.


Although each of these bonds appears to be covalent, the electronegativity of each atom determines how “greedy” it is for electrons – and this means that many bonds that look “neutral” are actually polarized.

Why is this important? Because attraction between opposite charges is the ultimate driving force in so many chemical reactions. You can see how these “hidden” partial charges provide an important clue for how these reactions proceed.

Note – the arrows show the movement of a pair of electrons (electrons truly are to organic chemistry what currency is to economics – it’s all about the study of their flow).

2-hidden charges

Note how the arrows always flow from negative to positive – never the opposite way.

It’s why a knowledge of electronegativity trends is absolutely crucial to doing well in organic chemistry.

Chapter 06 Amines
Chapter 07 Aromaticity
Chapter 9 Carbohydrates
Chapter 11 Conformations and Cycloalkanes


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